Why identification has to come before any action
Cleaning products are chemicals. Mixing an unknown substance with an acid, a chlorine-based product or a strong alkali can produce a reaction, and the person doing it is standing directly over it. A liquid on a floor might be water, coolant, a process chemical, a decanted solvent or something spilled from a container somebody moved. Nothing about its appearance reliably distinguishes those cases.
The site is the only party that can answer the question, because it holds the safety data sheets, the manifest and the knowledge of what is used where. That is why the rule routes the decision back to the site rather than asking a cleaner to make a reasonable guess. A reasonable guess is exactly what the controls around hazardous materials exist to prevent. A cleaner following the rule is not being unhelpful; they are applying the same control the site applies to its own staff, which is the outcome any responsible operator would want.
